| dc.contributor.author | Batanero, Belen | |
| dc.contributor.author | Recio, Javier | |
| dc.contributor.author | Barba, Fructuoso | |
| dc.date.accessioned | 2024-02-05T08:39:45Z | |
| dc.date.available | 2024-02-05T08:39:45Z | |
| dc.date.issued | 2016-05-25 | |
| dc.identifier.citation | Electrochemistry Communications 66 (2016) 29–33 | es |
| dc.identifier.issn | 1388-2481 | |
| dc.identifier.uri | https://hdl.handle.net/10115/29588 | |
| dc.description.abstract | The terpenoid cycloalkanones Fenchone and Menthone have been oxidized at a platinumanode under neutral and
alkaline electrolyte conditions. When NaClO4 was used as electrolyte, Fenchone (1a) afforded 1-isopropyl-4-
methyl-2-oxa-bicyclo[2.2.1]heptan-3-one, and Menthone (1b) provided the stable lactone 6-isobutyl-4-
methyl-tetrahydropyran-2-one, both in good yield.When using Na2CO3 as electrolyte, the oxidation of 1a gave
the fragrance-analogue 2,2-dimethyl-3-(2-oxopropyl) cyclopentanone in only one-pot. Mechanism proposals
are presented. | es |
| dc.language.iso | eng | es |
| dc.publisher | ELSERVIER | es |
| dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
| dc.subject | Anode | es |
| dc.subject | Six-membered lactones | es |
| dc.subject | Electrolytes | es |
| dc.subject | Fenchone and Menthone | es |
| dc.subject | Amperometric conditions | es |
| dc.subject | Rearrangement | es |
| dc.subject | Jasmonoid | es |
| dc.subject | Cyclopentanone | es |
| dc.title | One-pot anodic lactonization of Fenchone and Menthone and electrosynthesis of a new magnolione analogue | es |
| dc.type | info:eu-repo/semantics/article | es |
| dc.identifier.doi | 10.1016/j.elecom.2016.02.018 | es |
| dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | es |
Solange nicht anders angezeigt, wird die Lizenz wie folgt beschrieben: Attribution-NonCommercial-NoDerivatives 4.0 Internacional